Geological and structural position ofkapitanivsko-derenyukhynskiyultrabasitecomplexis given in the article. Features of Earth Crust deep framework of Golovanivska suture zone are considered. Geology of Pobuzka group serpentinitemassifs is described. Ore and petrological characteristic of Kapitanivskiy ultrabasic massif (Middle Pobuzhzhya) is represented. Description of new potential minable types of ore deposits were specified within the Kapitanivskiy massif for the first time. Native rhenium and platinum-group elements contained in sulphoarsenids such as osmium, iridium, ruthenium, rhodium and platinum were revealed as a result of mineragraphic, electron microscope and microprobe studies. At least two ore types of native rhenium and PGE within the Kapitanivskiy ore field are predicted by the preliminary data.